Since @atomzed 's 5* tier Guide and Ranking has become a bit outdated, I decided to whip up a new tier list as a temporary placeholder until someone else can put together a more comprehensive 5* tier guide. This will be just a bare bones tier list with perhaps some quick notes to aid players in their understanding of the 5* meta. Rankings will be open to the community for debate. Also do keep in mind this list is strictly focused on competitive viability.
5* tier ranking for PvP
Tier key
S tier: A character that is required to play PvP competitively or what some would call an “OP” character. Not having this character on your team will significantly hinder your ability to compete. (think 5* Gambit in his prime)
A tier: A character that is a pillar of the meta and/or is often found on the main teams of competitive players.
B tier: A character that is strong but not meta defining. When partnered with an A tier character, can perform reasonably well but falls a bit short in terms of speed or as a defensive deterrent in comparison to top meta teams.
C tier: A character that is of average strength and utility. Can beat the top meta team with the right partner but not speedily. Depending on who this character is teamed with and shield usage, it should allow a player to reach the 1200 progression reward. A top tier 4* character when boosted might be the better option for a player.
D tier: A character that is below average in strength and utility and has no obvious use for competitive play. Can beat the top meta team with the right partner but the player will find it difficult and time consuming. Might have some niche use, but in general, if used will open up the player to being attacked. A top tier 4* character when boosted is more likely to be the better option for a player.
F tier: A character that is very weak and more of a hindrance than help. A top tier 4* character when boosted is definitely the better option for a player.
The PvP tier list
S tier: N/A
A tier: Apocalypse, Beta Ray Bill, , Colossus, Mighty Thor, Okoye, Omega Red, Professor X, Scarlet Witch, Shang-Chi
B tier: Carnage, Chasm, Crystal, Deadpool, Electro, Gargantos, God Emperor Doom, Goose, Hit-Monkey, High Evolutionary, Iceman, Immortal Hulk, Jean Grey, Kang, Kitty Pryde, Knull, Onslaught, Riri Williams, Ronan, She-Hulk, Thanos, Thor, Venomsaurus Rex
C tier: Adam Warlock, Arcade, Big Wheel, Black Bolt, Black Panther, Black Suit Spider-Man*, Black Widow, Cable, Cyclops, Daredevil Matt Murdock, Doctor Strange, Elektra, Emma Frost, FA Captain America, Gambit, Gamora, Green Goblin, Havok, Hawkeye, Heimdall, Hela, Jessica Jones, Iron Man, IW Captain America, Kamala Khan, Killmonger, Kingpin, Loki, Magik, Mr. Sinister, Odin, PP Spider-Man, Sersi, Silver Surfer, Spider-Gwen, Star-Lord, Storm, The Hulk, Ultron, Vulture, Wolverine (Samurai Daken), Yelena Belova, Yellowjacket
D tier: Abigail Brand, Archangel, Captain Marvel, Doctor Octopus, Ghost Rider, Magneto, Miles Morales, Peggy Carter, Rescue, Symbiote Jeff, Wolverine (OML)
F tier: Wasp,
Current top PvP meta teams: 5* Colossus/Scarlet Witch, Apocalypse/Beta, Okoye/Scarlet Witch
Viable alternatives: Beta/Polaris, Iceman/Professor X, Beta/Kitty Pride, Shang-Chi/5* Colossus,
Special mention: Black Panther/Thanos, Immortal Hulk/Okoye for shield hopping
Notes:
-The ideal Okoye/Thor team setup is having Okoye 12 levels higher than Thor
- Black Suit Spider-man is a hard counter to Kitty/Rocket teams but unless you have a high 5* character, expect to take a lot of hits and struggle to reach 1200. He adds very little offensively and is used primarily to ensure your team doesn’t die fighting Kitty/Rocket. Recommended partners: Thor, DD
- Silver Surfer is a decent counter against Bishop and Worthy Cap teams but could certainly use a buff as his match damage is low and damage output still a bit wanting.
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5* tier ranking for PvE (Up to CL 9)
I actually spent a bit of time thinking about how to do this list as PvE is a fundamentally different beast in comparison to PvP. To put it simply, if you want to be competitive and rank well in PvE you will need Thanos. And if you have a high level 4* Rocket and Groot and a Guardian of the Galaxy teammate or a 5* Kitty Pryde, you will be pretty much set for most of the nodes in PvE. There will occasionally be times when the 5* Essential boosted character might have high enough match damage that it will rival the Grocket/Guardian for speed but such characters are few and far between.
The only situations where other 5* might be relevant are on wave nodes and the 5* Essential node. So I guess I will focus the ranking on those areas but keep in mind I am basing this mostly on my own experience and roster. The rate of success will differ depending on the level of your 5* characters and there may be instances when you have a higher leveled character that will perform better than what is ranked here. And remember, this ranking is open to debate. I am not really satisfied with it and open to suggestions on how to make it better.
Also note, this tier list does not apply to CL10 which has a distinctly different meta.
Tier key
S tier: A character that is required to play PvE competitively or what some might call an “OP” character. Not having this character will significantly hinder your ability to compete.
A tier: A character that will significantly improve your clear times, either by allowing you to quickly complete normal nodes, wave nodes or 5* essential nodes.
B tier: A character that may significantly improve your clear times when paired with a good partner. Not bad especially when partnered with an A tier character, but if this character is the best member on your main A team for PvE, you will struggle to make it t20 in competitive brackets. Using a boosted 4* may be the better option.
C tier: A character that will help you complete the more difficult nodes and wave nodes successfully but isn’t likely to help you break top 20 in a competitive bracket. Good for those looking to complete PvE event without having to use too many health packs.
? tier: Besides during the 5* essential boost, these characters will not allow you to compete for t10. Perhaps there is some synergy with 3* or 4* characters that may make them viable. If so, please let me know. But in most circumstances, using a boosted 4* will be the better option.
The PvE tier list
S tier: Thanos
A tier: Adam Warlock, Apocalypse, Black Panther, Colossus, Dr. Strange, Immortal Hulk, Kitty Pryde, Okoye, Shang-Chi, Thor
B tier: Beta Ray Bill, Deadpool, Daredevil, Hela, Jessica Jones, Onslaught, Professor X, PP Spider-Man, Sersi, Star-Lord, Yelena Belova
C tier: Black Bolt, God Emperor Doom, Havok, Hawkeye, Heimdall, IW Captain America*, Knull, Ronan, Scarlet Witch, Silver Surfer, Storm, Wolverine (OML), Wolverine (Samurai Daken), Yelena, Yellowjacket
? tier: Archangel, Black Suit Spider-man*, Black Widow, Cable, Captain Marvel, Carnage, Doctor Octopus, Electro, FA Captain America, Gambit, Ghost Rider, Green Goblin, Iceman, Iron Man, Jean Grey, Killmonger, Kingpin, Loki, Mr. Sinister, Odin, Rescue, The Hulk, Wasp
Notes:
- IW Captain America has been noted to be good against Boss fights because of his Red Coup de Grace being a major nuke.
- Black Suit Spider-Man is useful in the fight against Kaecilius in Strange Sights
Meta team composition guide for PvE:
-The first 3 easy nodes: 5* or 3* Thanos, 5* characters with high match damage or 4* Rocket and Groot (1 match to end the battle) or 4* Juggernaut, 4* Rocket and Grocket + any Guardians of the Galaxy character (note: not as fast as Thanos team but good for those looking to cut down on health pack use)
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The next three difficult nodes: 5Thanos/5 Kitty/4* Rocket and Groot, 5* Thanos, high level or maxed out 4Rocket and Groot, plus another Guardian character (match times will vary depending on opponent strength and cascades but initial 4 clears should take about 2 minutes)/Potentially comparable: 5 Okoye/4Medusa/3Thanos (use 2 TU boost before match), 5* Okoye/4Spider-man 2099/3 Thanos (use 2 TU boost before match), 5* Okoye/5* Thor/ Spider-man 2099
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The three essential nodes: 5* Thanos and 4* Rocket and Groot, 5* Thanos and 5* 50% Daredevil** (build dependent, if there is too wide a disparity between Thanos and DD speed is potentially lost), 5* Thanos and 5* Boosted character
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5* Essential node (fully champed 5*): Boosted 5* character, Thor/America Chavez, Thor/Okoye, Kitty/4* Grocket
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5* Essential node (low covered 5*): Boosted 5* character, Thor/America Chavez, Thor/Okoye, Daredevil/Gamora, Kitty/4*Grocket
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Good for wave nodes: 5* Thanos/Black Panther/Boosted 5* character, 5* Thanos/Black Panther/Dr. Strange, 5* Thanos/Kitty/4Grocket, 5 Thanos/4Grocket/Guardian partner, Potentially comparable: 5 Okoye/4Medusa/3Thanos (use 2 TU boost before match), 5* Okoye/4Spider-man 2099/3 Thanos (use 2 TU boost before match), Okoye/5* Thor/4* Human Torch
Alternative for long wave nodes: Kitty/4Grocket/5 Thor
-Not fast but effective is 5* Hawkeye, 4* Agent Caulson and 4* Carol
- Note: the 5* Okoye/4* Medusa/3* Thanos team is also fast. As always, this is roster dependent. If your Okoye is considerably higher than 5* Thanos and/or Kitty, it may be your fastest option.
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PvE CL 10
Feel free to chime in if you have any experience playing CL10. Still not sure which teams are the best of the best.
S tier: Okoye, Apocalypse
A tier: Adam Warlock**, Colossus, Emma Frost, Immortal Hulk, Kamala Khan**, Kang, Kitty Pryde, Omega Red, Shang-Chi, Thor
B tier: Beta Ray Bill, Chasm, Crystal, Magik, Onslaught, Professor X, Sersi, Thanos (for easy nodes), Wong
C tier: Big Wheel, Gamora, Hawkeye, Hit-Monkey, Iceman, Knull, Mighty Thor, Riri Williams, Ronan, Scarlet Witch, Yelena Belova (for enemy teams that rely on AP generation of goons), Yellowjacket
Please note: Adam is best paired with a booster like Okoye or Apocalypse.
Kamala Khan is best paired with Apocalypse & BRB plus supports that generate yellow/black
Effective teams
Adam Warlock/Immortal Hulk/Okoye** (Ideally with Okoye tanking for Adam; I believe you need her to be near max level or use a support that boosts her yellow or black match damage)
Apocalypse/5* Kamala Khan/Polaris [requires: supports that generate yellow. Ideally, black and/or green too]
Apocalypse/Immortal Hulk/Valkyrie
Apocalypse/Immortal Hulk/5 Thor
Apocalypse/Immortal Hulk/Beta Ray Bill
Apocalypse/Beta Ray Bill/Kamala Khan [requires: supports that generate yellow/black and use of AP boosts]
Apocalypse/Kamala Khan/ 5 Thor (Gladiator)
Apocalypse/Gorr/ 5 Thor (Gladiator)
Gorr/Okoye/5 Thor (Gladiator)
Okoye/Immortal Hulk/3* Thanos
Okoye/5 Thor/4 Scorpion
Okoye/5 Thor/4 Sabertooth
Okoye/5 Thor/4 Human Torch
Kitty/4* Rocket and Groot/4* Juggernaut
iHulk/4* Vulture/4* Karolina Dean (recommended iHulk build: 3/5/5, also use boosts to get your 4* flying asap)
5* Deadpool/Okoye/5Thor
4 Polaris/Kitty/4* Grocket
4* Polaris/Kitty/BRB
4* Polaris/BRB/Okoye
4* Polaris/BRB/Sersi
4* Polaris/halfThor/5* Okoye
4* Valkyrie/Melinda May/Shang-Chi
Okoye/Onslaught/Prof X
Shang-Chi/5* Thor/4* America Chavez
Shang-Chi/4* Nick Fury/4* America Chavez (best with support that gives yellow AP at start of match, yellow AP boost)
Shang-Chi/Onslaught/4America Chavez
Shang-Chi/4 Valkyrie/4* America Chavez
Challenge node teams
5* Beta Ray Bill/4* Polaris/1* Juggernaut
5* Deadpool/Okoye/5Thor
5 Kang (or 3* Kang if you have a decent levelled 5* Hawkeye)/Hawkeye/Iron Man + Support that gives yellow AP at beginning of match
5* Kang/5* Hawkeye/4* Deadpool
4* Polaris/Kitty/4* Grocket
4* Polaris/Kitty/BRB
4* Polaris/BRB/Okoye
4* Polaris/BRB/Sersi
4* Polaris/halfThor/5* Okoye
Okoye/5* Thor/5 Iceman
Okoye/5 Thor/ Spider-man 2099
5Hawkeye/Coulson/4 Gamora
5Hawkeye/Worthy Cap/4 Gamora
Shang-Chi/Onslaught/Sersi
For easy nodes featuring Mindless Ones
Chasm/iHulk/Thanos
*Note: Ideally you want Immortal Hulk tanking as little as possible. Ideally, you want him getting boosted from Okoye or Apocalypse but be aware if he tanks more colors than them you are going to burn through health packs. Supports that boost match damage is one possible work around.