In general you won’t particularly need more than one PW per colour, Angels Embrace as so far been the only event requiring multiple PWs of a single colour. Nodes of Power has always been one of each colour and the other events usually are 3 nodes each with a different colour.
Dual PWs are more flexible in terms of usability for nodes but also cost more crystals. That being said they’re often worth it, having access to 2 colours for deckbuilding is a big advantage.
As for which PWs to aim for? Ultimately this will depend on what’s currently being offered in the vault and the cards you have available as having certain cards can pull you towards particular PWs. I’ll try and list a few good all around PWs though.
Red: Koth is a great choice for red, hes slightly limited by being only red and having only red mana gains but having +9 to red matches makes him very fast if he gets going. Great choice for quick battle too.
Nahiri is also a very solid pick here and also has access to white, making her a bit more flexible than Koth is. Like Koth she’s also very solid for quick battle and her first and third abilities are very useful.
Blue: You already have Jace2 who is a solid pick here. The other blue PW I’d recommend to look out for is Kiora, who is also green. IMO she’s one of the best PWs in the game and all 3 of her abilities are useful and aren’t dependant on having particular cards like some other PWs are. You can’t really go wrong with Kiora, she’s a solid good all around pick.
Green: Again, Kiora is a great pick here. Between Kiora and Nissa1 you shouldn’t particularly need any other green PWs strictly for access to green nodes. Arlinn may be worth a look if you happen to get any decent werewolves though.
White: Nahiri is a good pick here, as is Sorin. Sorin has access to black as well and can also work reasonably well even without access to those higher rarity cards. Cards like Lone Rider, Grip of Desolation and Serene Steward all work well in a Sorin deck and are only uncommon. Sorin does have the lowest HP in the game though, but has plenty of ways to regain life so generally your effective health ends up being slightly higher than this. Very useful for objectives where you need to manipulate your health.
Black: Aside from Sorin, the other PW I’ll mention is Ob Nixilis. While Ob Nixilis is only mono black, he’s a very effective PW. There’s a bunch of different ways you can build an Ob deck, a lot of people go creatureless and rely on the ultimate ability but the other two abilities are very solid too, card draw and creature removal are never bad things to have access to.
Though maybe not as strong as some of the other options, Jace1, Gideon1 and Liliana1 are all decent picks if you’re just looking to fill out colours being that they only cost 50 crystals each (though it used to be only 10, was the price increase really necessary?).
In general, try to aim to have at least 1 PW in each colour first, then expand from there.